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Elements of quantistica mechanics

1)       Equations of Hamilton - Jacobi:

they are equations in a position to completely describing the temporal evolution of a system of which the hamiltoniana is famous.

 

2)       Comparison between the waves and the systems particle classics:

Position, speeds and energy of a classic particle can be defined with infinite precision while for a wave if x are famous the k are not famous and viceversa.

 

3)       Causes of the crisis of the classic mechanics:

The following effects do not find explanation with the classic mechanics:

Phantom of emission of the black body

The classic theory of Rayleigh and Jeans has determined that for l the energy emitted from the black body stretches to infinite, while in the truth experiments stretches they to 0, the hypothesis of Planck is that the exchange of energy between the walls of the black body and the cancellation happens in quantizzata shape multiple of a how much and0= hn .

Photoelectric effect

Draft of the electron emission from invested part of a solid one from a light bundle, experimentally is had that if the frequency of the photon incident is smaller of a minimum not it independently extracts no electron from the photon number incidents while if the frequency is greater enough also a single photon in order to extract an electron and the number is proporziona them to the number of photons incidents. The explanation came supplied from Einstein which it assumed that the electromagnetic wave yields to electrons energy in multiples of how much elementary and0= hn .

Atomic model of Bohr

The phantom of emission of an atom turns out characterized from lines very distinguished, the reason of that has been found in the model of Bohr which it previews that the electrons can ruotare around to the nucleus only on stationary orbits very defined from the quantization of the angular moment and that on such orbits the electrons do not emit cancellation.

 

4)       Wavelength of De Broglie:

relation important in how much alloy is one one largeness to corpuscolare to one ondulatoria largeness.

 

5) Equation of Schroedinger:

 

6) Principle of correspondence:

 

7) Equation of continuity:

 

8) Product to climb of wave functions:

 

9) Expected value of an observable one:

in the case of operating hermitiani it is had that the expected value is one real largeness.

 

10) Solution of the equation of Schroedinger in the case of upgrades them independent from the time:

It is possible to decompose upgrades them in the product f(r,t) = T(t) u(r) that for the part employee from the time it has solution while the part employee from the time from place to the equation to the autovalori that general solution has .

 

11) Principle of indetermination:

it is a principle that derives from not the commutatività between the operating position and the operating momentum.

 

12) Function of wave of the free particle:

Draft of a flat wave and the electron has momentum .

 

13) Function of wave of the particle in a hole of upgrades them to infinite walls:

Assuming it upgrades them null between â?"a and to and ¥ to the outside, it is had that the levels of granted energy assume values and the function of wave for n uneven is worth while for n equal is worth .

 

14) Function of wave of the particle in a hole of upgrades them to ended walls:

Assuming it upgrades them null between â?"a and to and U0 to the outside, one finds that the energetic levels son those that satisfy the important equations for equal solutions and for uneven solutions being and .

 

15) Energies quantizzate in the case of a harmonic oscillator:

The energetic levels allowed are therefore have a not null minimal energy for n = 0 and the quantici levels are distance to you between they of multiples of .

 

16) Probability of Tunneling:

The probability of Tunneling diminishes esponenzialmente to increasing of the larghezza d of the barrier that is .

 

17) Density of states in the cases three-dimensional, bidimensional, monodimensional:

In the case of the free particle 3D is had, for the particle in a hole of upgrades them to infinite walls that is free 2D has while for the quantico thread that is the free particle 1D is had

 

18) Function of distribution for classic particle, fermion, bosone:

The distribution function f(E) represents the probability that the state to energy and has of being occupied, for a classic particle has the distribution of Maxwell-Boltzmann , for fermions it characterizes to you from spin semintero instead has the Fermi-Dirac distribution and finally for the bosoni having spin entire the function of distribution of Bose-Einstein is had .